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BLEVE ( ), is an acronym for boiling liquid expanding vapor explosion. This is a type of explosion that can occur when a vessel containing a pressurized liquid is ruptured. Such explosions can be extremely hazardous.

A BLEVE results from the rupture of a vessel containing a liquidsubstantially above its atmospheric boiling point. The substance is stored partly in liquid form, with a gaseous vapour above the liquid filling the remainder of the container.

If the vessel is ruptured — for example, due to corrosion, or failure under pressure — the vapour portion may rapidly leak, lowering the pressure inside the container. This sudden drop in pressure inside the container causes violent boiling of the liquid, which rapidly liberates large amounts of vapour. The pressure of this vapour can be extremely high, causing a significant wave of overpressure (an explosion) which may completely destroy the storage vessel and project fragments over the surrounding area.

BLEVEs can also be caused by an external fire near the storage vessel causing heating of the contents and pressure build-up. While tanks are often designed to withstand great pressure, constant heating can cause the metal to weaken and eventually fail. If the tank is being heated in an area where there is no liquid, it may rupture faster without the liquid to absorb the heat. Gas containers are usually equipped with relief valves that vent off excess pressure, but the tank can still fail if the pressure is not released quickly enough.

A BLEVE can occur even with a non-flammable substance such as water, liquid nitrogen, liquid helium or other refrigerants or cryogens, and therefore is not usually considered a type of chemical explosion. However, if the substance involved is flammable, it is likely that the resulting cloud of the substance will ignite after the BLEVE has occurred, forming a fireball and possibly a fuel-air explosion, also termed a vapor cloud explosion (VCE). If the materials are toxic, a large area will be contaminated.

Significant industrial BLEVEs include accidents at Feyzinmarker in Francemarker in 1966, Kingman, Arizonamarker in 1973, Texas City, Texasmarker in 1978, Murdock, Illinoismarker in 1983 and San Juan Ixhuatepec in Mexico Citymarker in 1984. In 1978, a BLEVE occurred after a road accident with an LPG truck in the Los Alfaques Disastermarker in Spainmarker.

Some fire mitigation measures are listed under liquefied petroleum gas.

In the firefighting community, BLEVE is sometimes used as a humorous backronym for "big loud explosion very exciting" or "blast leveling everything very effectively."

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