Coesite is a form (
polymorph) of
silicon dioxide SiO2 that is formed
when very high pressure (2–3
gigapascals)
and moderately high temperature (700 °C) are applied to
quartz.
Coesite was first synthesized by Loring Coes, Jr., a chemist at the Norton Company
, in 1953. In 1960, coesite was found by
Edward C. T. Chao, in
collaboration with Eugene
Shoemaker, to naturally occur in the Barringer
Crater
, which was evidence that the crater must have been
formed by an impact.
The presence of coesite in unmetamorphosed rocks may be evidence of
a meteorite
impact event or of an
atomic bomb explosion. In metamorphic
rocks, coesite commonly is one of the best mineral indicators of
metamorphism at very high pressures (UHP, or ultrahigh-pressure
metamorphism). Such UHP metamorphic rocks record subduction or
continental collisions in which crustal rocks are carried to depths
of 70 km or more. Coesite also has been identified in
eclogite xenoliths from the mantle of the earth
that were carried up by ascending magmas;
kimberlite is the most common host of such
xenoliths.
The molecular structure of coesite consists of four silicon dioxide
tetrahedra arranged in a ring. The rings
are further arranged into a chain. This structure is
metastable within the stability
field of quartz: coesite will eventually decay back into quartz
with a consequent volume increase, although the
metamorphic reaction is very slow at
the low temperatures of the Earth's surface.
See also
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