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A nuclear chain reaction occurs when one nuclear reaction causes an average of one or more nuclear reactions, thus leading to a self-propagating number of these reactions. The specific nuclear reaction may be the fission of heavy isotopes (e.g. 235U) or the fusion of light isotopes (e.g. 2H and 3H). The nuclear chain reaction is unique since it releases several million times more energy per reaction than any chemical reaction.


The concept of a nuclear chain reaction was first realized by Hungarianmarker scientist Leó Szilárd in 1933. He filed a patent for his idea of a simple nuclear reactor the following year.

The total quantitative chain chemical reactions theory was created by Soviet physicist N.N.Semyonov in 1934. The idea of the chain reactions, developed by Semyonov, is the basis of various high technologies using the incineration of gas mixtures. The idea was also used for the description of the nuclear reaction..

In 1936, Szilárd attempted to create a chain reaction using beryllium and indium, but was unsuccessful. In 1939, Szilárd and Enrico Fermi discovered neutron multiplication in uranium, proving that a chain reaction was indeed possible. This discovery prompted the letter from Albert Einstein to President Franklin D. Roosevelt warning of the possibility that Nazi Germany might be attempting to build an atomic bomb.

Enrico Fermi created the first artificial self-sustaining nuclear chain reaction, called Chicago Pile-1marker (CP-1), in a racquets court below the bleachers of Stagg Fieldmarker at the University of Chicagomarker on December 2, 1942. Fermi's experiments at the University of Chicago were part of Arthur H. Compton's Metallurgical Laboratory facility, which was part of the Manhattan Project.

In 1956, Paul Kuroda of the University of Arkansasmarker postulated that a natural fission reactor may have once existed. Since nuclear chain reactions only require natural materials (such as water and uranium), it is possible to have these chain reactions occur where there is the right combination of materials within the Earth's crust. Kuroda's prediction was verified with the discovery of evidence of natural self-sustaining nuclear chain reactionsmarker in the past at Oklomarker in Gabon, Africa in September 1972.

Fission chain reaction

Fission chain reactions occur because of interactions between neutrons and fissile isotopes (such as 235U). The chain reaction requires both the release of neutrons from fissile isotopes undergoing nuclear fission and the subsequent absorption of some of these neutrons in fissile isotopes. When an atom undergoes nuclear fission, a few neutrons (the exact number depends on several factors) are ejected from the reaction. These free neutrons will then interact with the surrounding medium, and if more fissile fuel is present, some may be absorbed and cause more fissions. Thus, the cycle repeats to give a reaction that is self-sustaining.

Nuclear power plants operate by precisely controlling the rate at which nuclear reactions occur, and that control is maintained through the use of several redundant layers of safety measures. Moreover, the materials in a nuclear reactor core and the uranium enrichment level make a nuclear explosion impossible, even if all safety measures failed. On the other hand, nuclear weapons are specifically engineered to produce a reaction that is so fast and intense it cannot be controlled after it has started. When properly designed, this uncontrolled reaction can lead to an explosive energy release.

Nuclear fission fuel

Nuclear fission weapons must use an extremely high quality, highly-enriched fuel exceeding the critical size and geometry (critical mass) in order to obtain an explosive chain reaction. The fuel for a nuclear fission reactor is very different, usually consisting of a low-enriched oxide material (e.g. UO2). It is impossible for a nuclear power plant to undergo an explosive nuclear chain reaction. Chernobylmarker was a steam explosion, not a nuclear explosion. Furthermore, all power plants licensed in the United States require a negative void coefficient of reactivity, which completely eliminates the possibility of the accident that occurred at Chernobyl (which was due to a positive void coefficient).

Fission reaction products

When a heavy atom undergoes nuclear fission it breaks into two or more fission fragments. Also, several free neutrons, gamma rays, and neutrinos are emitted, and a large amount of energy is released. The sum of the rest masses of the fission fragments and ejected neutrons is less than the sum of the rest masses of the original atom and incident neutron (of course the fission fragments are not at rest). The mass difference is accounted for in the release of energy according to the equation E=Δmc²:

mass of released energy = \frac{E}{c^2} = m_\mbox{original}-m_\mbox{final}

Due to the extremely large value of the speed of light, c, a small decrease in mass is associated with a tremendous release of active energy (for example, the kinetic energy of the fission fragments). This energy (in the form of radiation and heat) carries the missing mass, when it leaves the reaction system (total mass, like total energy, is always conserved). While typical chemical reactions release energies on the order of a few eV (e.g. the binding energy of the electron to hydrogen is 13.6 eV), nuclear fission reactions typically release energies on the order of hundreds of millions of eVs.

Two typical fission reactions are shown below with average values of energy released and number of neutrons ejected:

{}^{235}U + \mbox{neutron} \rightarrow \mbox{fission fragments} + 2.4\mbox{ neutrons} + 192.9\mbox{ MeV}
{}^{239}Pu + \mbox{neutron} \rightarrow \mbox{fission fragments} + 2.9\mbox{ neutrons} + 198.5\mbox{ MeV}

Note that these equations are for fissions caused by slow-moving (thermal) neutrons. The average energy released and number of neutrons ejected is a function of the incident neutron speed. Also, note that these equations exclude energy from neutrinos since these subatomic particles are extremely non-reactive and, therefore, rarely deposit their energy in the system.

Timescales of nuclear chain reactions

Prompt neutron lifetime

The prompt neutron lifetime, l, is the average time between the emission of neutrons and either their absorption in the system or their escape from the system. The term lifetime is used because the emission of a neutron is often considered its "birth," and the subsequent absorption is considered its "death." For thermal (slow-neutron) fission reactors, the typical prompt neutron lifetime is on the order of 10−4 seconds, and for fast fission reactors, the prompt neutron lifetime is on the order of 10−7 seconds. These extremely short lifetimes mean that in 1 second, 10,000 to 10,000,000 neutron lifetimes can pass.

Mean generation time

The mean generation time, Λ, is the average time from a neutron emission to a capture that results in fission. The mean generation time is different from the prompt neutron lifetime because the mean generation time only includes neutron absorptions that lead to fission reactions (not other absorption reactions). The two times are related by the following formula:

\Lambda = \frac{l}{k}

In this formula, k is the effective neutron multiplication factor, described below.

Effective neutron multiplication factor

The effective neutron multiplication factor, k, is the average number of neutrons from one fission that cause another fission. The remaining neutrons either are absorbed in non-fission reactions or leave the system without being absorbed. The value of k determines how a nuclear chain reaction proceeds:

  • k 1 (subcriticality): The system cannot sustain a chain reaction, and any beginning of a chain reaction dies out over time. For every fission that is induced in the system, an average total of 1/(1 − k) fissions occur.

  • k = 1 (criticality): Every fission causes an average of one more fission, leading to a fission (and power) level that is constant. Nuclear power plants operate with k = 1 unless the power level is being increased or decreased.

  • k > 1 (supercriticality): For every fission in the material, it is likely that there will be "k" fissions after the next mean generation time. The result is that the number of fission reactions increases exponentially, according to the equation e^{(k-1)t/\Lambda}, where t is the elapsed time. Nuclear weapons are designed to operate under this state. There are two subdivisions of supercriticality: prompt and delayed.

When describing kinetics and dynamics of nuclear reactors and also in the practice of reactor operation is used the concept of Reactivity , which characterizes the deflection of reactor from the critical state. ρ=(k-1)/k.

In a nuclear reactor, k will actually oscillate from slightly less than 1 to slightly more than 1, due primarily to thermal effects (as more power is produced, the fuel rods warm and thus expand, lowering their capture ratio, and thus driving k lower). This leaves the average value of k at exactly 1. Delayed neutrons play an important role in the timing of these oscillations.

In an infinite medium, the multiplication factor may be described by the four factor formula.

Prompt and delayed supercriticality

Not all neutrons are emitted as a direct product of fission, some are instead due to the radioactive decay of some of the fission fragments. The neutrons that occur directly from fission are called "prompt neutrons," and the ones that are a result of radioactive decay of fission fragments are called "delayed neutrons." The fraction of neutrons that are delayed is called β, and this fraction is typically less than 1% of all the neutrons in the chain reaction.

The delayed neutrons allow a nuclear reactor to respond several orders of magnitude more slowly than just prompt neutrons would alone. Without delayed neutrons, changes in reaction rates in nuclear reactors would occur at speeds that are too fast for humans to control.

The region of supercriticality between k = 1 and k = 1/(1-β) is known as delayed supercriticality (or delayed criticality). It is in this region that all nuclear power reactors operate. The region of supercriticality for k > 1/(1-β) is known as prompt supercriticality (or prompt criticality), which is the region in which nuclear weapons operate.

The change in k needed to go from critical to prompt critical is defined as a dollar

Neutron multiplication in nuclear weapons

Nuclear fission weapons require a mass of fissile fuel that is prompt supercritical.

For a given mass of fissile material the value of k can be increased by increasing the density. Since the probability per distance traveled for a neutron to collide with a nucleus is proportional to the material density, increasing the density of a fissile material can increase k. This concept is utilized in the implosion method for nuclear weapons. In these devices, the nuclear chain reaction begins after increasing the density of the fissile material with a conventional explosive.

In the gun-type fission weapon two subcritical pieces of fuel are rapidly brought together. The value of k for a combination of two masses is always greater than that of its components. The magnitude of the difference depends on distance, as well as the physical orientation.

The value of k can also be increased by using a neutron reflector surrounding the fissile material

Once the mass of fuel is prompt supercritical, the power increases exponentially. However, the exponential power increase cannot continue for long since k decreases when the amount of fission material that is left decreases (i.e. it is consumed by fissions). Also, the geometry and density are expected to change during detonation since the remaining fission material is torn apart from the explosion.


Detonation of a nuclear weapon involves bringing fissile material into its optimal supercritical state very rapidly. During part of this process, the assembly is supercritical, but not yet in an optimal state for a chain reaction. Free neutrons, in particular from spontaneous fissions, can cause the device to undergo a preliminary chain reaction that destroys the fissile material before it is ready to produce a large explosion, which is known as predetonation. To keep the probability of predetonation low, the duration of the non-optimal assembly period is minimized and fissile and other materials are used which have low spontaneous fission rates. In fact, the combination of materials has to be such that it is unlikely that there is even a single spontaneous fission during the period of supercritical assembly. In particular, the gun method cannot be used with plutonium (see nuclear weapon design).

Fusion chain reaction

In a more generalized sense, a nuclear fusion reaction can be considered a nuclear chain reaction: it occurs under extreme pressure and temperature conditions, which are maintained by the energy released in the fusion process.

See also


  1. L. Szilárd, "Improvements in or relating to the transmutation of chemical elements," British patent number: GB630726 (filed: 28 June 1934; published: 30 March 1936). esp@cenet document view
  3. H. L. Anderson, E. Fermi, and Leo Szilárd, "Neutron production and absorption in uranium," The Physical Review, vol. 56, pages 284–286 (1 August 1939). Available on-line at: .
  5. Oklo: Natural Nuclear Reactors—Fact Sheet

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